I would contact Technical Support to look into the issue even if the pdf link is not working you should normally still have the tab. You should still have a tab that states attached pdf but when you click on it the screen would be blank.
I would test the Sample Library to see how it behaves.
You may need to recover your library.
Please contact Technical Support directly
1-800-336-4474 option 4 then 1 or
https://endnote.com/contact/