How to start from specific reference number in Endnote web or desktop

I am writing a long thesis, and I am writing it as sperated chapters in word 2007, I want to start references in chapter two as example ref. number 100…etc, after i finsh all the chapters that make it easy to collect in one thesis without problems in references.  Now my problem how to start in new word document specific number of ref. !!!

any idea please ??

In the Format Paper settings on the layout tab.

Word 2007 and 2010 : On the EndNote tab, in the Bibliography group, click the bottom corner arrow.
On the Layout tab, change this setting:

“Start with bibliography number:”  Enter a starting reference number.

but unlike formating all the chapters in a single document, if you repeat a reference in a subsequent chapter, you will repeat the reference using this workflow. 

Thank you for your replay